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The formation of HCN and NH 3 from the pyrolysis of coal (and biomass) is discussed based on our experimental data as well as the data in the literature, including the pyrolysis of N-containing pyrrolic and pyridinic model compounds reported in the literature. The pyrolysis of the model compounds and the thermal cracking of coal pyrolysis volatiles appear to be in good qualitative agreement...
The formation of HCN and NH 3 during the pyrolysis of a biomass (bagasse) and a set of rank-ordered coal samples has been studied in a novel reactor. The reactor has some features of both a drop-tube reactor and a fixed-bed reactor: the reactor allows the coal/biomass particles to be heated up rapidly as well as to be held for a pre-specified period of time at peak temperature. The experimental...
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