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Owing to the innovative applications of fluorinated compounds in many areas of technology and medicine, methods for the preparation of C−F quaternary fluorine containing compounds are in extremely high demand. Here, we report the discovery of a general procedure for an SN2 reaction catalyzed by Pd/Ding‐SKP‐type ligands, and that occurs between Colby pro‐enolates with MBH carbonates to afford the corresponding...
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