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Enantioselective carboaminations of olefins constitute an attractive strategy for a rapid increase in molecular complexity from readily available starting materials. Reported here is an intermolecular asymmetric carboamination of acrylates using rhodium(III)‐catalyzed alkenyl C−H activations of N‐enoxysuccinimides to generate the nitrogen and carbon portion for the transfer. A rhodium complex equipped...
Enantioselective carboaminations of olefins constitute an attractive strategy for a rapid increase in molecular complexity from readily available starting materials. Reported here is an intermolecular asymmetric carboamination of acrylates using rhodium(III)‐catalyzed alkenyl C−H activations of N‐enoxysuccinimides to generate the nitrogen and carbon portion for the transfer. A rhodium complex equipped...
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