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The kinetics of the reactions of phenol and six substituted phenols with oxomanganese(IV) tetra(2-N-methylpyridyl)porphyrin in aqueous solution (pH 7.7) have been studied. The reactions are shown to be first order in both phenol and the oxomanganese(IV) species. The second order rate constants have been measured and the influence of the substituents on these values have been analyzed using Hammett...
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