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Three components for total control: Trisubstituted silyl enol ethers were prepared by three‐component coupling of α‐silyl α,β‐unsaturated ketones, organocopper reagents, and organic halides with complete regio‐ and stereoselectivity (see scheme). The reaction proceeded through a 1,3 migration of the silyl group via cyclic silicate intermediates, which controlled the configuration of the silyl enol...
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