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xLi2O–(100 − x)TeO2 (x = 20 and 25 mol%) and xV2O5–(25 − x)Li2O–75TeO2 (x = 1, 2, 3, 4 and 5 mol%) glasses were prepared by melt‐quenching and their thermal and structural properties were characterized by differential scanning calorimetry, Raman spectroscopy, high‐energy X‐ray diffraction and neutron diffraction and reverse Monte Carlo (RMC) simulations. The glass transition temperature increases...
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