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The N2 position of guanine (G) is one of the major sites for DNA modification by various carcinogens. Eight oligonucleotides with varying adduct bulk at guanine N2 were analyzed for catalytic efficiency and fidelity with human DNA polymerase (pol) η, which is involved in translesion synthesis (TLS). Pol η effectively bypassed N 2 -methyl(Me)G, N 2 -ethyl(Et)G, N 2 -isobutyl(Ib)G,...
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