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Like riding the wave cyclic voltammetry allows for the quantitative assessment of redox‐active and redox‐inactive guest binding to paramagnetic supramolecular complexes, which is described in the Full Paper by V. L. Pecoraro et al. on page 6786 ff.
A novel competitive binding assay was implemented to monitor the binding of a redox inactive substrate to a redox inactive metallacrown host based on its competition with ferrocene carboxylate (FcC−) using cyclic voltammetry (CV). First, the binding of FcC− to LnIII[15‐MC‐5] (LnMC) hosts was characterized by cyclic voltammetry. It was shown that the voltammetric half wave potentials,...
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