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Enantioselective synthesis of (S)-α-cyano-3-phenoxybenzyl alcohol [(S)-CPBA] was successfully achieved by lipase-catalyzed alcoholysis of (R,S)-CPBA acetate [(R,S)-CPBAc] in organic medium after systematic optimization of catalysts, water activity, organic solvents and acyl acceptors. A commercially available Pseudomonas fluorescens lipase, Lipase AK (Amano), showed excellent enantioselectivity (ee...
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