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Surface ligands are essential tools for the stabilization of colloidal nanoparticles (NPs) in solvents. However, knowledge regarding the effects of the ligand shell, especially the ligand length, is insufficient and controversial. Here we demonstrate solution‐based experiments on n‐alkylphosphonate‐capped TiO2 NPs to investigate the effects of ligand length and solution temperature on colloidal stability...
More than enough is too much! The cover shows a role of phosphonate ligand length in the colloidal stability of TiO2 nanoparticles. In contrast to classical colloid theory, the dodecylphosphonate ligand provided better colloidal stability than the longer or shorter n‐alkylphosphonate ligands. The proposed method is applicable to a wide range of colloidal nanoparticle systems. More information can...
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