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Self-assembled monolayer (SAM) films of phosphonates have been successfully formed via reaction of 11-hydroxyundecylphosphonic acid or 4,4′-di(methylenephosphonic acid)-2,2′-bipyridine with the oxide layer of copper via the Tethering by Aggregation and Growth (TBAG) deposition method. The hydroxyl-terminated SAM was further modified with isonicotinic acid or 4,4′-dicarboxy-2,2′-bipyridine through...
The performances of n-type DSCs containing the heteroleptic copper(I) dyes [Cu(1)(dmbpy)] + and [Cu(2)(dmbpy)] + (1=((6,6′-dimethyl-[2,2′-bipyridine]-4,4′-diyl)bis(4,1-phenylene))bis(phosphonic acid); 2=tetraethyl ((6,6′-dimethyl-[2,2′-bipyridine]-4,4′-diyl)bis(4,1-phenylene))bis(phosphonate); dmbpy=6,6′-dimethyl-2,2′-bipyridine) have been evaluated to determine whether or not deprotection...
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