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This paper addresses ignition histories of diffusion flames in unstrained hydrogen-air mixing layers for initial conditions of temperature and pressure that place the system below the crossover temperature associated with the second explosion limit of hydrogen–oxygen mixtures. It is seen that a two-step reduced chemical-kinetic mechanism involving as main species H 2 , O 2 , H ...
This paper addresses homogeneous ignition of hydrogen–oxygen mixtures when the initial conditions of temperature and pressure place the system below the crossover temperature associated with the second explosion limit. A three-step reduced mechanism involving H 2 , O 2 , H 2 O, H 2 O 2 and HO 2 , derived previously from a skeletal mechanism of eight...
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