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In the pursuit of CO2‐based materials, the development of efficient catalysts for the alternating copolymerization of CO2 and epoxides to give polycarbonates is receiving particular attention. Desirable attributes for such catalysts are high copolymerization activity at low CO2 pressure, as well as chemo‐ and stereocontrol over the formed polymer. Here, we report a novel chiral zinc catalyst that...
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