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Honeycomb‐shaped pores in metal–organic frameworks (MOFs) are capable of storing substantial quantities of gas, and especially porous materials with the capacity to adsorb and securely retain considerable amounts of hydrogen and carbon dioxide have attracted attention. Here, we report Zn‐MOFs with triptycene‐based ligands, which feature honeycomb‐shaped pores that exhibit efficient storage capabilities...
A series of metal–organic frameworks (MOFs) based on zinc ions and two triptycene ligands of different size have been synthesized under solvothermal conditions. Structural analyses revealed that they are isostructural 3D‐network MOFs. The high porosity and thermal stability of these MOFs can be attributed to the highly rigid triptycene‐based ligands. Their BET specific surface areas depend on the...