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We investigated the adsorption of a 6-dimers Si(100)2×1 surface as a function of coverage and adsorption type (molecular/dissociative) by first principle calculations. In particular, we performed calculations on models with 2, 3, 4 and 6 phenol molecules, corresponding to coverage Θ=0.34, 0.5, 0.67 and 1. We found that total adsorption energy, when at least one phenol is in a molecular state is lower...
Thermal desorption of phosphorus on Si(100) surfaces has been investigated by varying the phosphorus coverage from zero to one monolayer (ML). The reaction path of phosphorus desorption is complicated and strongly dependent upon the phosphorus coverage. In the thermal desorption spectra, there are three apparent desorption peaks at ∼750, ∼850 and ∼1000°C. The entire phosphorus atoms on the surface...
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