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The effect of pore-connectivity feature of nanoporous carbons (NPCs) on the adsorptive and diffusive behavior of methane was studied by a simple constricted carbon nanotube (C-CNT) model using grand canonical Monte Carlo and molecular dynamics simulations. In spite of slight overprediction, C-CNT model can properly predict the adsorption of methane in some real NPCs. The calculated heat of adsorption...
The knowledge about the adsorption and diffusion properties (specially about diffusion) of aluminophosphate molecular sieves is very scarce in the literature. These materials offer interesting properties as adsorbents as they have a polar framework and do not contain charge-balancing cations. In this work, the adsorption isotherms of nitrogen, methane and carbon dioxide over an AlPO4-11 sample synthesized...
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