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Reactions of HgII‐, TeIV‐, and SeVI‐containing starting materials under moderate hydrothermal conditions (230 °C, one week) resulted in the formation of the mercuric oxotellurate(IV)/oxoselenate(VI) phases Hg3SeTe2O10 and Hg3SeTe4O14. The mixed‐valent phase Hg5Se2O8 containing mercury in oxidation states +I and +II as well as selenium in oxidation states +IV and +VI also formed under these conditions...
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