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The quaternary germanides RE3TRh4Ge4 (RE = Ce, Pr, Nd; T = Nb, Ta) were synthesized from the elements by arc‐melting and subsequent annealing in a muffle furnace. The structure of Ce3TaRh4Ge4 was refined from single‐crystal X‐ray diffractometer data: new type, Pbam, a = 719.9(2), b = 1495.0(3), c = 431.61(8), wR2 = 0.0678, 1004 F2 values, and 40 variables. Isotypy of the remaining phases was evident...
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