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Oxozincates are obtained by reactions of ZnO with oxides of large cations like alkali, alkaline earth and rare earth metals. Zinc and oxygen are common elements of the anionic part of crystal structures, mostly forming ZnO4‐tetrahedra. In NaLiZnO2 and RbLiZnO2 the tetrahedra are simultaneously occupied by zinc and lithium atoms. Deviations from the coordination number four are rare. An example of...
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