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The new rare‐earth metal(III) oxotellurates(IV) RE2Te3O9 (RE=La−Nd) of the so far unknown A‐type structure can be obtained as needle‐shaped single crystals through solid‐state reactions of the corresponding binary oxides. Their crystal structures were determined as A1‐type for RE=La and Ce or A2‐type for RE=Pr and Nd by single‐crystal X‐ray diffraction. Both structure types crystallize in the monoclinic...
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