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Abstract. Twenty five ternary phosphides crystallizing with four different but closely related structure types were prepared using elemental tin as a flux. Their lattice constants are reported. New compounds include Sc2Fe12P7, Sc3.6Fe10.4P7, Y2Co12P7, and Hf2T12P7 with T = Fe, Co, Ni. They crystallize with the hexagonal Zr2Fe12P7 type structure, which was refined from single‐crystal X‐ray data of...
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