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Chemical shift in Ll and Lƞ X‐ray emission lines of 48Cd and 50Sn elements in various chemical compounds was determined with high resolution wavelength dispersive X‐ray fluorescence (WDXRF) spectrometer. The positive and negative shifts were measured in 48Cd compounds viz, CdS, CdB4O7, CdCl2, Cd3(PO4)2, CdCO3, CdI2 and CdO with reference to pure Cd foil and 50Sn compounds viz, Sn(CrO4)2, SnO, SnO2...
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