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Ionic Crystals
In article number 2300743, Sayaka Uchida, Takashi Tachikawa, and co‐workers demonstrate a convenient method to obtain few‐atom silver clusters. Silver clusters with three, four, or six atoms emitting blue, green, or red colors are formed and stabilized in redox‐active porous ionic crystals (PICs). The cluster size is controlled by the degree of electron transfer from the PIC to silver...
Ag clusters with a controlled number of atoms have received significant interest because they show size‐dependent catalytic, optical, electronic, or magnetic properties. However, the synthesis of size‐controlled, ligand‐free, and air‐stable Ag clusters with high yields has not been well‐established. Herein, it is shown that isostructural porous ionic crystals (PICs) with redox‐active polyoxometalates...
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