The relatively high recombination rate of charges remains the most critical limiting factor for solar‐driven water splitting for hydrogen generation. Herein, a tandem 0D/2D/2D NbS2 quantum dot/Nb2O5 nanosheet/g‐C3N4 flake (NSNOCN) system is designed. Owing to the unique spatial‐arrangement and elaborate morphology of 0D NbS2, 2D Nb2O5, and 2D g‐C3N4 in the newly designed NSNOCN, plenty of spatial charge–transfer cascades from g‐C3N4 to NbS2 via Nb2O5 are formed to accelerate separation and transfer of charges significantly, thus contributing to a high photocatalytic H2 generation rate of 13.99 mmol h−1 g−1 (an apparent quantum efficiency of 10.8% at 420 nm), up to 107.6 and 43.7 times by contrast with that of g‐C3N4 and Nb2O5, respectively. This work can provide a new platform in the design of artificial photocatalytic systems with high charge–transfer efficiency.