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In this paper some basic assumptions underlying the chemical derivatization analysis of polymer surfaces treated in nitrogen‐containing plasmas are critically examined. Imines, which are known to represent major constituents of such surfaces as well as of plasma polymers grown from amine precursors, show a very versatile chemical reactivity. For example, imines are generally able to exchange their...
The H2 plasma modification of polydimethylsiloxane (PDMS) films of initial thickness up to 600 nm was studied. The main plasma component modifying the films is the VUV plasma radiation measured by a VUV monochromator. By variation of the plasma processing parameters, such as H2 pressure, RF forward power and treatment time, the optimum parameters are defined for the plasma chemical modification of...
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