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In this theoretical research, we have investigated the substituent effect of singlet (s) and triplet (t) rNHGes with the fused various aromatic rings, at (U)B3LYP/AUG‐cc‐pVTZ and (U)M06‐2X/AUG‐cc‐pVTZ. All singlet and triplet rNHGes appear as minima and every singlet germylene displays more thermodynamic stability and more kinetic stability than its corresponding triplet state. Regarding to the relationship...
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