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A new class of partially fluorinated alternating aryl/alkyl vinylene ether (FAVE) polymers were prepared from addition polymerization of aryl trifluorovinyl ethers (TFVEs) with 1,4‐butanediol or 4‐hydroxybenzyl alcohol. Monodisperse FAVE telechelic polymers were also prepared possessing latent thermal reactivity which afforded chain‐extended perfluorocyclobutyl (PFCB) aryl ethers via step‐growth [2...
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