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In the present study, salicylaldimine zinc complex (Zn‐HMBED) was synthesized and its reactivity for the ring‐opening polymerization (ROP) of lactide was studied. The zinc complex was prepared by the reaction of zinc solution with one molar equivalent of salicylaldimine Schiff base ligand in methanol under a nitrogen atmosphere. Further, the complex was characterized by various spectroscopic methods,...
The multistep synthesis of four new acidic vinylcyclopropanes is described. These monomers were fully characterized using 1H NMR, 13C NMR and 31P NMR spectroscopy and high‐resolution mass spectrometry. The homopolymerization of the corresponding polymerizable di‐tert‐butyl phosphates as well as the copolymerization of each acidic monomer with 1,1‐diethoxycarbonyl‐2‐vinylcyclopropane were investigated...
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