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In the present study, salicylaldimine zinc complex (Zn‐HMBED) was synthesized and its reactivity for the ring‐opening polymerization (ROP) of lactide was studied. The zinc complex was prepared by the reaction of zinc solution with one molar equivalent of salicylaldimine Schiff base ligand in methanol under a nitrogen atmosphere. Further, the complex was characterized by various spectroscopic methods,...
Biodegradable supramolecular polymers (SMPs) were synthesized by the end‐functionalization of polylactide‐block‐poly(δ‐valerolactone)‐block‐polylactide (PLA–PVL–PLA) triblock copolymers with 2‐ureido‐4[1H]‐pyrimidinone (UPy) self‐complementary quadruple hydrogen‐bonding units. The end‐functionalized PLA–PVL–PLA copolymers exhibit the typical characteristics of thermoplastic elastomers. Thermal properties,...
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