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Phase separation of polymer mixtures induced by photo‐crosslinking and photopolymerization is summarized from the viewpoint of competing interactions in polymeric systems. First, the kinetics of photo‐crosslinking and photopolymerization are reviewed with particular emphasis on the Trommsdorff − Norrish effect in polymerization, which leads to the formation of a bimodal distribution of molecular weight...
A series of poly(urethane‐urea‐amide) thermoplastic elastomers (PUUAs) based on polytetrahydrofuran (polytetramethylene glycol, PTMG), nylon‐6 and 4,4′‐diphenylmethane diisocyanate were synthesized through reactive processing. This method solved the incompatibility of nylon‐6 and PTMG, and these model elastomers were used to gain insight into the structure–property relations of block polymers. The...
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