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We have investigated temperature‐induced Raman spectral changes of deuterated water in an ionic liquid, 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([bmim][BF4]), between room temperature and 77 K. The comparison of the OH and OD stretching vibrational spectra at 77 K shows that the strength of the hydrogen bonds in [bmim][BF4]–water mixtures strongly depends on the type of water, i.e. H2O and D...
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