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The Continuum in the variation of the X‐Z bond length change from blue‐shifting to red‐shifting through zero‐ shifting in the X‐Z‐‐‐Y complex is inevitable. This has been analyzed by ab‐initio molecular orbital calculations using Z= Hydrogen, Halogens, Chalcogens, and Pnicogens as prototypical examples. Our analysis revealed that, the competition between negative hyperconjugation within the donor...
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