Carbothermal reduction and nitridation (CRN) method, used for the synthesis of nitride‐based ceramic powders, is an effective and economic technique that has been widely investigated. In this study, a CRN‐based novel approach, denominated as dynamic/thermochemical method (DTM), has been used to synthesize submicron high‐purity aluminum nitride (AlN) powders with equiaxed‐sized particles. DTM is a modified CRN method in which the reaction takes place in a controlled atmosphere using a rotary tube furnace, allowing the synthesis of fine particle‐size powders in a relatively short time. Following the DTM process, homogeneous submicron AlN powders were synthesized from a mixture of aluminum hydroxide (Al(OH)3) and carbon black at 1450°C for 1.5 h. Furthermore, dynamic synthesis parameters, as well as the use of ammonia (NH3) and propane (C3H8) gas mixtures instead of carbon black and nitrogen, were investigated.