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A computer simulation study describing the electrophoretic separation and migration of methadone enantiomers in presence of free and immobilized (2‐hydroxypropyl)‐β‐CD is presented. The 1:1 interaction of methadone with the neutral CD was simulated by using experimentally determined mobilities and complexation constants for the complexes in a low‐pH BGE comprising phosphoric acid and KOH. The use...
In this work, electrophoretic preconcentration of protein and peptide samples in microchannels was studied theoretically using the 1D dynamic simulator GENTRANS, and experimentally combined with MS. In all configurations studied, the sample was uniformly distributed throughout the channel before power application, and driving electrodes were used as microchannel ends. In the first part, previously...
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