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The first example of application of nanosized polystyrene‐based cation exchanger (NSCE) with sulfo groups as a dynamic coating of capillary walls was demonstrated. The conditions of dynamic coating formation were optimized and ensured the long‐term stability of the coating. Capillary‐to‐capillary and day‐to‐day repeatabilities were 4% and 3%, correspondingly. The NSCE coating stability at various...
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