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A chromium‐mediated synthesis of enantiopure sugar‐based halocyclopropanecarboxamides is reported. This reaction can be stereospecifically carried out on (E)‐ or (Z)‐α,β‐unsaturated amides and takes place with the formation of a new C‐Hal stereogenic center, which is generated with total stereoselectivity. Synthetic applications of the obtained halocyclopropanecarboxamides are also reported. The structure...
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