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Herein, in situ generated efficient catalysts were designed for fixation of CO2 to cyclic carbonates under mild conditions. Zinc bromide and N,N‐dibenzyl‐N,N‐dimethylammonium bromide, being proved as active catalyst species, were in situ generated from cheap Zn powder, dimethyl formamide and benzyl bromide, and catalyzed the cycloaddition reaction of CO2 and various terminal epoxides in moderate to...
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