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A novel planar chiral flavinium salt, 3‐benzyl‐5‐ethyl‐10‐(8‐phenylnaphthalen‐1‐yl)isoalloxazinium perchlorate (2b), which bears a phenyl cap that covers one side of the isoalloxazinium skeleton plane, has been prepared as a potential catalyst for the enantioselective H2O2 oxidation of sulfides. The rate of H2O2 oxidation of sulfides in the presence of racemic 2b is comparable to that of the reaction...
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