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2‐Substituted benzo[b]furans can easily be assembled from simple phenols, boronic acids or other organoboron reagents, and trichloroethylene. The overall process requires only two synthetic steps, with the key step being a one‐pot sequential Suzuki cross‐coupling/direct arylation reaction. The method tolerates many useful functional groups and does not require the installation of any other activating...
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