Redox inert cations are increasingly featuring participating in non‐innocent structural aggregation roles. The six‐coordinate bis‐pyrazolate pyridine pincer (L) complex LFeII(DMAP)3 (DMAP = 4‐dimethylaminopyridine) is oxidized, to FeIII, by excess silver triflate. All beta nitrogen atoms of the pyrazolate rings bind Ag+, to create a species with two linear N–Ag–N units parallel to the linear Fe–O‐Fe unit, in [LFe(DMAP)2Ag]2O2+. Excess silver triflate oxidizes LCoII(PEt3)2 to form CoL2Ag4(OTf)2(PEt3)2+ as its triflate salt, and this has a bis‐pincer CoIII center where two pyrazolate nitrogen atoms carry Ag(PEt3)+ groups and the other two carry AgOTf groups. Finally, deprotonation of the free‐base ligand, H2L, with potassium hydride leads to [K2L]n. The structure again shows the electrophiles K+ interacting with all pincer nitrogen atoms, by multiple interactions of the empirical formula unit with neighbors of the same formula, to give a helical polymeric solid. This illustrates the general characteristics of this pincer ligand as multifunctional, using every available nitrogen to recruit exogenous electrophiles, and these features are discussed for their potential in multi‐metal aggregate‐building, for example, for their resulting magnetic properties.