We report the modular synthesis of donor–photosensitizer–bridge–acceptor (D–P–B–A) triads and D–P dyads for the formation of photoinduced charge‐separated species. The structures are based on a phenothiazine unit (D), a bis(terpyridine) [bis(tpy)] ruthenium(II) complex (P), several phenylene(ethynylene)‐type spacer units (B), and a pyrrolidino[60]fullerene entity (A). The donor–acceptor distance is between 18 and 37 Å and was varied by four different bridging units. The photophysical and electrochemical characterization revealed certain interactions between the active moieties in the ground and the excited state. In particular, a reduced ruthenium‐based emission in the triads indicates the occurrence of a quenching process mediated by the fullerene entity. Strong electrostatic interactions between the ruthenium(II) complex and the pyrrolidino[60]fullerene have been observed for the shortest triad, resulting in the strongest electron‐accepting pyrrolidino[60]fullerene unit in the series.