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With a bigger birefringence than calcite, sodium nitrate (NaNO3) single crystal might have potential applications in fiber‐optic polarizer, opto‐isolators and polarizing prisms. However, it is difficult to grow large‐size NaNO3 crystals for their thermal conductivity anisotropy and phase transition at 275°C. In this paper, crack‐free NaNO3 crystals with size of Φ20×100 mm3 were prepared by Bridgman...
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