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Conventional and microwave assisted synthesis of new series of N‐[2‐{2‐(substituted phenyl)‐4‐oxo‐5‐(substituted benzylidene)‐1,3‐thiazolidine}‐iminoethyl]‐2‐aminothiazole 5a–5m have been developed. The cycloaddition reaction of thioglycolic acid with N‐{2‐(substituted benzylidenehydrazino)‐ethyl}‐2‐aminothiazole 3a–3m in the presence of anhydrous ZnCl2 afforded new heterocyclic compounds N‐[2‐{2‐(substituted...
An efficient, highly selective method for polyfluoroalkylation of 2‐aminothiazole derivatives was described. Specifically, a di‐polyfluoroalkylated derivative was produced when 2‐amino‐4‐chloromethylthiazole was reacted with perfluoroalkyl iodides under very mild conditions.
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