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α‐Cyclodextrin was shown to be convenient chemical shift reagent for determination of the enantiomeric composition of α‐hydroxyphosphonic acids by means of 31P NMR. The developed methodology appeared to be reliable, repetitive, easy to perform and simple for interpretation. Enantiomeric discrimination in the 31P NMR spectra for 12 of 13 studied hydroxyphosphonates was achieved, with baseline separation...
The enantioselective hydrogenation of methyl or ethyl pyruvate over cinchona‐platinum catalyst system (Orito's reaction) is one of the most intensively studied heterogeneous catalytic asymmetric hydrogenation reactions. Studies aiming at systematic changes of the chiral template have played a crucial role in creating hypotheses for the mechanism of Orito's reaction. It is very important to clarify...
This article describes a computational study on dimeric zinc porphyrin tweezer complexes with primary/secondary amines and secondary alcohols that validates the use of Optimized Potential for Liquid Simulations (OPLS‐2005) as the lead computational choice for assisting the tweezer methodology in the absolute configurational assignment of organic compounds. A supramolecular, microscale approach known...
Two novel optically active terthiophene and bithiophene monomers bearing at the C‐β position of thiophene ring an enantiomerically pure chiral alkyl group, namely 3,3″‐di[2‐((S)‐(+)‐2‐methylbutoxy)ethyl]‐2,2′:5′,2″‐terthiophene and 3,3′‐di[2‐((S)‐(+)‐2‐methylbutoxy)ethyl]‐2:2′‐bithiophene, have been synthesized and characterized. Being symmetrically substituted, their polymerization adopting simple...
A comparative study of the Vibrational circular dichroism (VCD) patterns in three bicyclic terpenes with related molecular structures, (+)‐(R)‐α‐pinene, (−)‐(S)‐β‐pinene, and (−)‐(S)‐verbenone, is carried out. The study is done in the light of normal mode descriptions from a previous vibrational analysis. Although normal modes corresponding to identical molecular moieties shown the same description,...
Effective drug delivery systems for biopharmaceuticals, such as proteins, peptide‐based drugs, and vaccines still present major challenges. A procedure has been developed whereby human serum albumin (HSA) can be used as a delivery vehicle for these biomolecules exploiting its role as main fatty acid carrier. Using essentially fatty acid free HSA (HSAff) it is possible to form stable complexes with...
Flavopiridol is a potent cyclin‐dependant kinase (CDK) inhibitor and is in clinical trials for anticancer treatment. A limiting factor in its drug development has been the high dosage required in human clinical trials. The high dosage is suggested to be necessary because of significant flavopiridol binding to human blood serum. Albumin is the major protein component of blood serum and has been suggested...
Synchrotron radiation circular dichroism (SRCD) is a well‐established method in structural biology. The first UV‐VIS beamline dedicated to circular dichroism at Diamond Light Source, a third generation synchrotron facility in South Oxfordshire, has recently become operational and it is now available for the user community. Herein we present an important application of SRCD: the CD measurement of protein...
Because of the increased use of circular dichroism (CD) spectroscopy as a routine technique by nonspecialists to determine the conformational/configurational properties of biomolecules, we have decided to present here some criteria to accurately check the ordinate scale calibration of a CD spectrometer particularly in the critical low‐wavelength UV region, to understand, and correct, where possible,...
The electronic circular dichroism (CD) spectra were recorded for three diastereomeric eclipsed–staggered pairs of charge‐transfer cyclophanes with different substituents, i.e., (4Rp;12Rp)‐ and (4Sp;12Rp)‐12,15‐dimethoxy[2.2]paracyclophane‐4,7‐dicarboxylic acid derivatives (1a‐c and 2a‐c, where a, b, and c denote methyl ester, carboxylic acid, and carboxylate, respectively). The effects of altering...
The formation of an inclusion complex between γ‐cyclodextrin and Ln DOTA has been reported in the literature. All Ln DOTA complexes in solution give rise to a network of equilibria between different stereoisomers, which are pairs of enantiomers. By means of near infrared circular dichroism of the Yb derivative, we demonstrate that upon the formation of the host–guest complex, there is a complete stereoselection...
The optical rotation of natural amino acids becomes more positive when the medium is changed from approximately neutral to strongly acidic (Clough–Lutz–Jirgensons (CLJ) effect). In this work, it is shown by time–dependent density functional computations that the effect can be generalized to other α–substituted chiral carboxylic acids. The physical origin of the generalized CLJ effect is similar to...
Circular dichroism (CD) has become an increasingly important tool in the study of biological molecules as it enables structural information to be obtained nondestructively on solution‐phase samples. However, sample requirements for CD are often seen as being too high with protein backbone measurements in standard cuvettes typically requiring ∼100–300 μL of 0.1 mg/ml protein. To address this issue,...
The application of the Cartesian coordinate tensor transfer (CCT) technique for simulations of the IR absorption and vibrational circular dichroism (VCD) spectra of relatively large nucleic acid fragments is demonstrated on several case studies. The approach is based on direct ab initio calculations of atomic tensors, determining molecular properties, for relatively small fragments, and subsequent...
We report on the experimental‐theoretical analysis of degenerated two‐photon absorption circular‐linear dichroism (2PA‐CLD) in (S)‐(−)‐1,1′‐bi(2‐naphthol) and (R)‐(+)‐1,1′‐bi(2‐naphthol) dissolved in THF. 2PA‐CLD reveals similarities and differences between optical polarization states for the different enantiomers. These results unveil the potential applications of 2PA‐CLD for the study and identification...
Six enantiomeric pairs of TADDOL‐s gathered in two series with either methyl (series A) or phenyl (series B) substituent in 2‐position of the dioxolane ring were studied by vibrational circular dichroism (VCD). Experimental IR and VCD spectra associated with density functional theory (DFT) calculations showed that the two series exhibit quite different conformations in solution. In series A, the conformer...
Our efforts on the synthesis of peptides with well‐characterized secondary structures, combined with detailed spectroscopic investigations, most of them performed in collaboration with internationally recognized experts, have allowed us to publish the electronic (electronic circular dichroism) and vibrational (FTIR absorption, vibrational circular dichroism, Raman, and Raman optical activity) signatures...
The nπ* and ππ* transitions of polypeptides mix significantly with very high energy transitions in the poly(Pro)II conformation, as evidenced by the strongly nonconservative CD spectrum in the 170–250 nm region. Because of this, the exciton model, the standard quantum mechanical model for predicting absorption and CD spectra of polypeptides, gives poor results for the poly(Pro) II (PII) conformation,...
The Soai reaction amplifies small enantiomeric excesses in a spectacular manner. Being known for 20 years, it has drawn the attention of many scientists in different fields as it is to date the only chemical reaction offering the chance to study the phenomenon of asymmetric autocatalysis in conjunction with high amplification of enantiomeric excess (ee). This mini‐review comprises an introduction...
FreeMarker template error (HTML_DEBUG mode; use RETHROW in production!)
Java method "org.springframework.web.servlet.support.RequestContext.getMessage(String)" threw an exception when invoked on org.springframework.web.servlet.support.RequestContext object "org.springframework.web.servlet.support.RequestContext@68c745e0"; see cause exception in the Java stack trace.
----
FTL stack trace ("~" means nesting-related):
- Failed at: ${springMacroRequestContext.getMessag... [in template "META-INF/freemarker-templates/spring.ftl" in macro "message" at line 28, column 22]
- Reached through: @spring.message "portal.searchResult... [in template "META-INF/freemarker-templates/portal/search/facets.ftl" at line 149, column 33]
----
Java stack trace (for programmers):
----
freemarker.core._TemplateModelException: [... Exception message was already printed; see it above ...]
at freemarker.ext.beans._MethodUtil.newInvocationTemplateModelException(_MethodUtil.java:289)
at freemarker.ext.beans._MethodUtil.newInvocationTemplateModelException(_MethodUtil.java:261)
at freemarker.ext.beans.OverloadedMethodsModel.exec(OverloadedMethodsModel.java:65)
at freemarker.core.MethodCall._eval(MethodCall.java:65)
at freemarker.core.Expression.eval(Expression.java:81)
at freemarker.core.DollarVariable.calculateInterpolatedStringOrMarkup(DollarVariable.java:96)
at freemarker.core.DollarVariable.accept(DollarVariable.java:59)
at freemarker.core.Environment.visit(Environment.java:363)
at freemarker.core.Environment.invoke(Environment.java:715)
at freemarker.core.UnifiedCall.accept(UnifiedCall.java:83)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.visit(Environment.java:369)
at freemarker.core.IteratorBlock$IterationContext.executedNestedContentForCollOrSeqListing(IteratorBlock.java:316)
at freemarker.core.IteratorBlock$IterationContext.executeNestedContent(IteratorBlock.java:272)
at freemarker.core.IteratorBlock$IterationContext.accept(IteratorBlock.java:243)
at freemarker.core.Environment.visitIteratorBlock(Environment.java:596)
at freemarker.core.IteratorBlock.acceptWithResult(IteratorBlock.java:108)
at freemarker.core.IteratorBlock.accept(IteratorBlock.java:94)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.process(Environment.java:306)
at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
at freemarker.core.Environment.visit(Environment.java:427)
at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.process(Environment.java:306)
at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
at freemarker.core.Environment.visit(Environment.java:427)
at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.process(Environment.java:306)
at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
at freemarker.core.Environment.visit(Environment.java:427)
at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
at freemarker.core.Environment.visit(Environment.java:327)
at freemarker.core.Environment.visit(Environment.java:333)
at freemarker.core.Environment.process(Environment.java:306)
at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
at org.springframework.web.servlet.view.tiles3.TilesView.renderMergedOutputModel(TilesView.java:132)
at pl.edu.icm.synat.common.ui.tiles.FreeMarkerAndTilesView.renderMergedOutputModel(FreeMarkerAndTilesView.java:148)
at org.springframework.web.servlet.view.AbstractView.render(AbstractView.java:303)
at org.springframework.web.servlet.DispatcherServlet.render(DispatcherServlet.java:1243)
at org.springframework.web.servlet.DispatcherServlet.processDispatchResult(DispatcherServlet.java:1027)
at org.springframework.web.servlet.DispatcherServlet.doDispatch(DispatcherServlet.java:971)
at org.springframework.web.servlet.DispatcherServlet.doService(DispatcherServlet.java:893)
at org.springframework.web.servlet.FrameworkServlet.processRequest(FrameworkServlet.java:965)
at org.springframework.web.servlet.FrameworkServlet.doGet(FrameworkServlet.java:856)
at javax.servlet.http.HttpServlet.service(HttpServlet.java:620)
at org.springframework.web.servlet.FrameworkServlet.service(FrameworkServlet.java:841)
at javax.servlet.http.HttpServlet.service(HttpServlet.java:727)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:303)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at org.apache.tomcat.websocket.server.WsFilter.doFilter(WsFilter.java:52)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:316)
at org.springframework.security.web.access.intercept.FilterSecurityInterceptor.invoke(FilterSecurityInterceptor.java:126)
at org.springframework.security.web.access.intercept.FilterSecurityInterceptor.doFilter(FilterSecurityInterceptor.java:90)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.access.ExceptionTranslationFilter.doFilter(ExceptionTranslationFilter.java:114)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.session.SessionManagementFilter.doFilter(SessionManagementFilter.java:122)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.AnonymousAuthenticationFilter.doFilter(AnonymousAuthenticationFilter.java:111)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.rememberme.RememberMeAuthenticationFilter.doFilter(RememberMeAuthenticationFilter.java:149)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.servletapi.SecurityContextHolderAwareRequestFilter.doFilter(SecurityContextHolderAwareRequestFilter.java:168)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.savedrequest.RequestCacheAwareFilter.doFilter(RequestCacheAwareFilter.java:48)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.FilterChainProxy.doFilterInternal(FilterChainProxy.java:207)
at org.springframework.security.web.FilterChainProxy.doFilter(FilterChainProxy.java:184)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.AbstractAuthenticationProcessingFilter.doFilter(AbstractAuthenticationProcessingFilter.java:205)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.jasig.cas.client.session.SingleSignOutFilter.doFilter(SingleSignOutFilter.java:100)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.AbstractAuthenticationProcessingFilter.doFilter(AbstractAuthenticationProcessingFilter.java:205)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.logout.LogoutFilter.doFilter(LogoutFilter.java:120)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.authentication.logout.LogoutFilter.doFilter(LogoutFilter.java:120)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.header.HeaderWriterFilter.doFilterInternal(HeaderWriterFilter.java:64)
at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.context.request.async.WebAsyncManagerIntegrationFilter.doFilterInternal(WebAsyncManagerIntegrationFilter.java:53)
at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.session.ConcurrentSessionFilter.doFilter(ConcurrentSessionFilter.java:133)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.context.SecurityContextPersistenceFilter.doFilter(SecurityContextPersistenceFilter.java:91)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.access.channel.ChannelProcessingFilter.doFilter(ChannelProcessingFilter.java:152)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.saml.metadata.MetadataGeneratorFilter.doFilter(MetadataGeneratorFilter.java:87)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at pl.edu.icm.synat.portal.web.security.PortalLocaleFilter.doFilterInternal(PortalLocaleFilter.java:51)
at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
at org.springframework.security.web.FilterChainProxy.doFilterInternal(FilterChainProxy.java:213)
at org.springframework.security.web.FilterChainProxy.doFilter(FilterChainProxy.java:176)
at org.springframework.web.filter.DelegatingFilterProxy.invokeDelegate(DelegatingFilterProxy.java:344)
at org.springframework.web.filter.DelegatingFilterProxy.doFilter(DelegatingFilterProxy.java:261)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at ch.qos.logback.classic.helpers.MDCInsertingServletFilter.doFilter(MDCInsertingServletFilter.java:51)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at org.springframework.web.filter.CharacterEncodingFilter.doFilterInternal(CharacterEncodingFilter.java:85)
at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at pl.edu.icm.synat.portal.web.security.RemoteIpFilter.doFilter(RemoteIpFilter.java:75)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at net.bull.javamelody.MonitoringFilter.doFilter(MonitoringFilter.java:219)
at net.bull.javamelody.MonitoringFilter.doFilter(MonitoringFilter.java:196)
at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
at org.apache.catalina.core.StandardWrapperValve.invoke(StandardWrapperValve.java:220)
at org.apache.catalina.core.StandardContextValve.invoke(StandardContextValve.java:122)
at org.apache.catalina.authenticator.AuthenticatorBase.invoke(AuthenticatorBase.java:504)
at org.apache.catalina.core.StandardHostValve.invoke(StandardHostValve.java:170)
at org.apache.catalina.valves.ErrorReportValve.invoke(ErrorReportValve.java:103)
at org.apache.catalina.core.StandardEngineValve.invoke(StandardEngineValve.java:116)
at org.apache.catalina.connector.CoyoteAdapter.service(CoyoteAdapter.java:421)
at org.apache.coyote.ajp.AjpProcessor.process(AjpProcessor.java:190)
at org.apache.coyote.AbstractProtocol$AbstractConnectionHandler.process(AbstractProtocol.java:611)
at org.apache.tomcat.util.net.JIoEndpoint$SocketProcessor.run(JIoEndpoint.java:314)
at java.util.concurrent.ThreadPoolExecutor.runWorker(ThreadPoolExecutor.java:1142)
at java.util.concurrent.ThreadPoolExecutor$Worker.run(ThreadPoolExecutor.java:617)
at org.apache.tomcat.util.threads.TaskThread$WrappingRunnable.run(TaskThread.java:61)
at java.lang.Thread.run(Thread.java:745)
Caused by: org.springframework.context.NoSuchMessageException: No message found under code 'portal.searchResult.facet.^journalVolume^journalNumber' for locale 'pl'.
at org.springframework.context.support.AbstractMessageSource.getMessage(AbstractMessageSource.java:159)
at org.springframework.context.support.DelegatingMessageSource.getMessage(DelegatingMessageSource.java:66)
at org.springframework.context.support.AbstractApplicationContext.getMessage(AbstractApplicationContext.java:1129)
at org.springframework.web.servlet.support.RequestContext.getMessage(RequestContext.java:712)
at org.springframework.web.servlet.support.RequestContext.getMessage(RequestContext.java:678)
at sun.reflect.GeneratedMethodAccessor295.invoke(Unknown Source)
at sun.reflect.DelegatingMethodAccessorImpl.invoke(DelegatingMethodAccessorImpl.java:43)
at java.lang.reflect.Method.invoke(Method.java:497)
at freemarker.ext.beans.BeansWrapper.invokeMethod(BeansWrapper.java:1458)
at freemarker.ext.beans.ReflectionCallableMemberDescriptor.invokeMethod(ReflectionCallableMemberDescriptor.java:56)
at freemarker.ext.beans.MemberAndArguments.invokeMethod(MemberAndArguments.java:51)
at freemarker.ext.beans.OverloadedMethodsModel.exec(OverloadedMethodsModel.java:61)
... 179 more