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Transamination of [Co{N(SiMe3)2}2]2 with C6H4(NHSiiPr3)2 gave the centrosymmetric trinuclear [{CoterN(SiMe3)2(μ‐η‐[o‐C6H4(κNSiiPr3)2])}2Coint] (1) (Coter, Coint=terminal, internal Co, respectively), with 3‐coordinate Coter, and Coint “sandwiched” between the o‐phenylenes of the two ligands; experimental and computational data support CoII centres and ditopic o‐amido‐imino‐cyclohexen‐allyl ligands;...
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