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A series of nickel complexes with nuclearity ranging from Ni3 to Ni6 have been obtained by treatment of a variety of nickel salts with the 2‐pyridylcyanoxime ligand. The reported compounds have as a common structural feature the triangular arrangement of nickel cations bridged by a central μ3‐oxo/alkoxo ligand. These compounds are simultaneously the first nickel derivatives of the 2‐pyridylcyanoxime...
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