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Chirality recognition in the hydrogen‐bonded glycidol⋅⋅⋅propylene oxide complex has been studied by using rotational spectroscopy and ab initio calculations. An extensive conformational search has been performed for this binary adduct at the MP2/6‐311++G(d,p) level of theory and a total of 28 homo‐ and heterochiral conformers were identified. The eight binary conformers, built of the two dominant...
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