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From the analysis of the polarizability of carbon nano‐onions (CNOs), it was concluded that CNOs behave as near perfect nanoscopic Faraday cages. If CNOs behave as ideal Faraday cages, the reactivity of the C240 cage should be the same in Li+@C240 and Li+@C60@C240. In this work, the Diels–Alder reaction of cyclopentadiene to the free C240 cage and the C60@C240 CNO together with their Li+‐doped counterparts...
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