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Multivalence affords imine‐based self‐assembled molecules more stability and even compatibility with water, a solvent where the imine bond is apt to undergo hydrolysis. For more information, see the Concept by H. Li et al. on page 13.
The formation of imine bond is reversible. This feature has been taken advantage of by chemists for accomplishing high yielding self‐assembly. On the other hand, it also jeopardizes the intrinsic stability of these self‐assembled products. However, some recent discoveries demonstrate that some of these imine bond containing molecules could be rather stable or kinetically inert. A deep investigation...
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