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We describe ferrocene‐based N‐heterocyclic germylenes and stannylenes of the type [Fe{(η5‐C5H4)NR}2E:] (1 RE; E=Ge, Sn; R=neopentyl (Np), mesityl (Mes), trimethylsilyl (TMS)), which constitute the first examples of redox‐functionalised N‐heterocyclic tetrylenes (NHTs). These compounds are thermally stable and were structurally characterised by means of X‐ray diffraction studies, except for the neopentyl‐substituted...
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